TY  - JOUR
UR  - http://stacks.iop.org/1742-6596/987/i=1/a=012031
T1  - Characterization of local atomic structure in Co/Zn based ZIFs by XAFS
A1  - Yulia Podkovyrina and Vera Butova and Elena Bulanova and Andriy Budnyk and Maria Kremennaya and Alexander Soldatov and Carlo
Lamberti
Y1  - 2018
SP  - 012031
JF  - Journal of Physics: Conference Series
VL  - 987
IS  - 1
SN  - 1742-6596
N2  - The local atomic structure in bimetallic Co/Zn zeolitic imidazolate frameworks (ZIFs) was studied
using X-ray Absorption Fine Structure (XAFS) spectroscopy and theoretical calculations. The
experimental Co K-edge and Zn K-edge XANES (X-ray Absorption Near Edge Structure) spectra of Zn 1-x
Co x C 8 H 10 N 4 samples (x = 0.05, 0.25, 0.75) synthesized by microwave synthesis were compared
with the data for the ZIF-67 (x=1) and ZIF-8 (x=0). Theoretical XANES spectra for the bimetallic
ZIFs were calculated. It was shown that in bimetallic ZIFs the Co and Zn atoms have the similar
local environment.
ER  -