TY  - JOUR
UR  - http://stacks.iop.org/1742-6596/712/i=1/a=012048
T1  - Atomic structure of PtCu nanoparticles in PtCu/C catalysts prepared by simultaneous and sequential
deposition of components on carbon support
A1  - L A Bugaev and V V Srabionyan and V V Pryadchenko and A L Bugaev and L A Avakyan and S V Belenov and V E Guterman
Y1  - 2016
SP  - 012048
JF  - Journal of Physics: Conference Series
VL  - 712
IS  - 1
SN  - 1742-6596
N2  - Nanocatalysts PtCu/C with different distribution of components in bimetallic PtCu nanoparticles
(NPs) were synthesized by simultaneous and sequential deposition of Cu and Pt on carbon support.
Electrochemical stability of the obtained samples PtCu/C was studied using the cyclic voltammetry.
Characterization of atomic structure of as prepared PtCu NPs and obtained after acid treatment was
performed by Pt L 3 - and Cu K -edge EXAFS using the technique for determining local structure
parameters of the absorbing atom under strong correlations among them. EXAFS derived parameters were
used for generation of structural models of PtCu NPs by the method of cluster simulations. Within
this approach, the models of atomic structure of PtCu NPs obtained by the two methods of synthesis,
before and after post treatment and after two months from their preparation were revealed.
ER  -